| 6.3.2 Methane and Nitrous Oxide The SAR reported that several studies found a higher forcing due to CH4 
  than IPCC (1990), up to 20%; however the recommendation was to use the same 
  value as in IPCC (1990). The higher radiative forcing estimates were obtained 
  using band models. Recent calculations using LBL and band models confirm these 
  results (Lelieveld et al., 1998; Minschwaner et al., 1998; Jain et al., 2000). 
  Using two band models, Myhre et al. (1998b) found the computed radiative forcing 
  to differ by almost 10%. This was attributed to difficulties in the treatment 
  of CH4 in band models since, given its present abundance, the CH4 
  absorption lies between the weak line and the strong line limits (Ramanathan 
  et al., 1987). After updating for a small increase in concentration since the 
  SAR, the radiative forcing due to CH4 is 0.48 Wm-2 since 
  pre-industrial times. This estimate for forcing due to CH4 is only 
  for the direct effect of CH4; for radiative forcing of the indirect 
  effect of CH4, see Sections 6.5 and 6.6. The problem mentioned above with the band models for CH4 does not 
  occur to the same degree in the case of N2O, given the latter’s 
  present concentrations. Three recent studies, Myhre et al. (1998b) (two models), 
  Minschwaner et al. (1998) (one model), and Jain et al. (2000) (one model), calculated 
  lower radiative forcing for N2O than reported in previous IPCC assessments, 
  viz., 0.13, 0.12, 0.11, and 0.12 Wm-2, respectively, compared to 
  0.14 Wm-2 in the SAR. For N2O, effects of change in spectroscopic 
  data, stratospheric adjustment, and decay of the mixing ratio in the stratosphere 
  are all found to be small effects. However, effects of clouds and different 
  radiation schemes are potential sources for the difference between the newer 
  estimates and the SAR. A value of 0.15 Wm-2 is now suggested for 
  the radiative forcing due to N2O, taking into account an increase 
  in the concentration since the SAR, together with a smaller pre-industrial concentration 
  than assumed in IPCC (1996a; Table 2.2) (see Chapter 4). |