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IPCC Fourth Assessment Report: Climate Change 2007 |
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Climate Change 2007: Working Group I: The Physical Science Basis TS.2.5 Net Global Radiative Forcing, Global Warming Potentials and Patterns of Forcing The understanding of anthropogenic warming and cooling influences on climate has improved since the TAR, leading to very high confidence that the effect of human activities since 1750 has been a net positive forcing of +1.6 [+0.6 to +2.4] W m–2. Improved understanding and better quantification of the forcing mechanisms since the TAR make it possible to derive a combined net anthropogenic radiative forcing for the first time. Combining the component values for each forcing agent and their uncertainties yields the probability distribution of the combined anthropogenic radiative forcing estimate shown in Figure TS.5; the most likely value is about an order of magnitude larger than the estimated radiative forcing from changes in solar irradiance. Since the range in the estimate is +0.6 to +2.4 W m–2, there is very high confidence in the net positive radiative forcing of the climate system due to human activity. The LLGHGs together contribute +2.63 ± 0.26 W m–2, which is the dominant radiative forcing term and has the highest level of scientific understanding. In contrast, the total direct aerosol, cloud albedo and surface albedo effects that contribute negative forcings are less well understood and have larger uncertainties. The range in the net estimate is increased by the negative forcing terms, which have larger uncertainties than the positive terms. The nature of the uncertainty in the estimated cloud albedo effect introduces a noticeable asymmetry in the distribution. Uncertainties in the distribution include structural aspects (e.g., representation of extremes in the component values, absence of any weighting of the radiative forcing mechanisms, possibility of unaccounted for but as yet unquantified radiative forcings) and statistical aspects (e.g., assumptions about the types of distributions describing component uncertainties). {2.7, 2.9} The Global Warming Potential (GWP) is a useful metric for comparing the potential climate impact of the emissions of different LLGHGs (see Table TS.2). Global Warming Potentials compare the integrated radiative forcing over a specified period (e.g., 100 years) from a unit mass pulse emission and are a way of comparing the potential climate change associated with emissions of different greenhouse gases. There are well-documented shortcomings of the GWP concept, particularly in using it to assess the impact of short-lived species. {2.10} Table TS.2. Lifetimes, radiative efficiencies and direct (except for CH4) global warming potentials (GWP) relative to CO2. {Table 2.14}
Errata | Global Warming Potential for Given Time Horizon |
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Industrial Designation or Common Name (years) | Chemical Formula | Lifetime (years) | RadiativeEfficiency (W m–2 ppb–1) | SAR‡ (100-yr) | 20-yr | 100-yr | 500-yr |
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Carbon dioxide | CO2 | See belowa | b1.4x10–5 | 1 | 1 | 1 | 1 | Methanec | CH4 | 12c | 3.7x10–4 | 21 | 72 | 25 | 7.6 | Nitrous oxide | N2O | 114 | 3.03x10–3 | 310 | 289 | 298 | 153 | Substances controlled by the Montreal Protocol |
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CFC-11 | CCl3F | 45 | 0.25 | 3,800 | 6,730 | 4,750 | 1,620 | CFC-12 | CCl2F2 | 100 | 0.32 | 8,100 | 11,000 | 10,900 | 5,200 | CFC-13 | CClF3 | 640 | 0.25 | | 10,800 | 14,400 | 16,400 | CFC-113 | CCl2FCClF2 | 85 | 0.3 | 4,800 | 6,540 | 6,130 | 2,700 | CFC-114 | CClF2CClF2 | 300 | 0.31 | | 8,040 | 10,000 | 8,730 | CFC-115 | CClF2CF3 | 1,700 | 0.18 | | 5,310 | 7,370 | 9,990 | Halon-1301 | CBrF3 | 65 | 0.32 | 5,400 | 8,480 | 7,140 | 2,760 | Halon-1211 | CBrClF2 | 16 | 0.3 | | 4,750 | 1,890 | 575 | Halon-2402 | CBrF2CBrF2 | 20 | 0.33 | | 3,680 | 1,640 | 503 | Carbon tetrachloride | CCl4 | 26 | 0.13 | 1,400 | 2,700 | 1,400 | 435 | Methyl bromide | CH3Br | 0.7 | 0.01 | | 17 | 5 | 1 | Methyl chloroform | CH3CCl3 | 5 | 0.06 | | 506 | 146 | 45 | HCFC-22 | CHClF2 | 12 | 0.2 | 1,500 | 5,160 | 1,810 | 549 | HCFC-123 | CHCl2CF3 | 1.3 | 0.14 | 90 | 273 | 77 | 24 | HCFC-124 | CHClFCF3 | 5.8 | 0.22 | 470 | 2,070 | 609 | 185 | HCFC-141b | CH3CCl2F | 9.3 | 0.14 | | 2,250 | 725 | 220 | HCFC-142b | CH3CClF2 | 17.9 | 0.2 | 1,800 | 5,490 | 2,310 | 705 | HCFC-225ca | CHCl2CF2CF3 | 1.9 | 0.2 | | 429 | 122 | 37 | HCFC-225cb | CHClFCF2CClF2 | 5.8 | 0.32 | | 2,030 | 595 | 181 | Hydrofluorocarbons |
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HFC-23 | CHF3 | 270 | 0.19 | 11,700 | 12,000 | 14,800 | 12,200 | HFC-32 | CH2F2 | 4.9 | 0.11 | 650 | 2,330 | 675 | 205 | HFC-125 | CHF2CF3 | 29 | 0.23 | 2,800 | 6,350 | 3,500 | 1,100 | HFC-134a | CH2FCF3 | 14 | 0.16 | 1,300 | 3,830 | 1,430 | 435 | HFC-143a | CH3CF3 | 52 | 0.13 | 3,800 | 5,890 | 4,470 | 1,590 | HFC-152a | CH3CHF2 | 1.4 | 0.09 | 140 | 437 | 124 | 38 | HFC-227ea | CF3CHFCF3 | 34.2 | 0.26 | 2,900 | 5,310 | 3,220 | 1,040 | HFC-236fa | CF3CH2CF3 | 240 | 0.28 | 6,300 | 8,100 | 9,810 | 7,660 | HFC-245fa | CHF2CH2CF3 | 7.6 | 0.28 | | 3,380 | 1030 | 314 | HFC-365mfc | CH3CF2CH2CF3 | 8.6 | 0.21 | | 2,520 | 794 | 241 | HFC-43-10mee | CF3CHFCHFCF2CF3 | 15.9 | 0.4 | 1,300 | 4,140 | 1,640 | 500 | Perfluorinated compounds | Sulphur hexafluoride | SF6 | 3,200 | 0.52 | 23,900 | 16,300 | 22,800 | 32,600 | Nitrogen trifluoride | NF3 | 740 | 0.21 | | 12,300 | 17,200 | 20,700 | PFC-14 | CF4 | 50,000 | 0.10 | 6,500 | 5,210 | 7,390 | 11,200 | PFC-116 | C2F6 | 10,000 | 0.26 | 9,200 | 8,630 | 12,200 | 18,200 |
Table TS.2 (continued) | | | | Global Warming Potential for Given Time Horizon |
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Industrial Designation or Common Name (years) | Chemical Formula | Lifetime (years) | RadiativeEfficiency (W m–2 ppb–1) | SAR‡ (100-yr) | 20-yr | 100-yr | 500-yr |
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Perfluorinated compounds (continued) | PFC-218 | | 2,600 | 0.26 | 7,000 | 6,310 | 8,830 | 12,500 | PFC-318 | | 3,200 | 0.32 | 8,700 | 7,310 | 10,300 | 14,700 | PFC-3-1-10 | | 2,600 | 0.33 | 7,000 | 6,330 | 8,860 | 12,500 | PFC-4-1-12 | | 4,100 | 0.41 | | 6,510 | 9,160 | 13,300 | PFC-5-1-14 | | 3,200 | 0.49 | 7,400 | 6,600 | 9,300 | 13,300 | PFC-9-1-18 | | >1,000d | 0.56 | | >5,500 | >7,500 | >9,500 | trifluoromethyl sulphur pentafluoride | | 800 | 0.57 | | 13,200 | 17,700 | 21,200 | Fluorinated ethers | HFE-125 | | 136 | 0.44 | | 13,800 | 14,900 | 8,490 | HFE-134 | | 26 | 0.45 | | 12,200 | 6,320 | 1,960 | HFE-143a | | 4.3 | 0.27 | | 2,630 | 756 | 230 | HCFE-235da2 | | 2.6 | 0.38 | | 1,230 | 350 | 106 | HFE-245cb2 | | 5.1 | 0.32 | | 2,440 | 708 | 215 | HFE-245fa2 | | 4.9 | 0.31 | | 2,280 | 659 | 200 | HFE-254cb2 | | 2.6 | 0.28 | | 1,260 | 359 | 109 | HFE-347mcc3 | | 5.2 | 0.34 | | 1,980 | 575 | 175 | HFE-347pcf2 | | 7.1 | 0.25 | | 1,900 | 580 | 175 | HFE-356pcc3 | | 0.33 | 0.93 | | 386 | 110 | 33 | HFE-449sl (HFE-7100) | | 3.8 | 0.31 | | 1,040 | 297 | 90 | HFE-569sf2 (HFE-7200) | | 0.77 | 0.3 | | 207 | 59 | 18 | HFE-43-10pccc124 (H-Galden 1040x) | | 6.3 | 1.37 | | 6,320 | 1,870 | 569 | HFE-236ca12 (HG-10) | | 12.1 | 0.66 | | 8,000 | 2,800 | 860 | HFE-338pcc13 (HG-01) | | 6.2 | 0.87 | | 5,100 | 1,500 | 460 | Perfluoropolyethers | PFPMIE | | 800 | 0.65 | | 7,620 | 10,300 | 12,400 | Hydrocarbons and other compounds – Direct Effects | Dimethylether | | 0.015 | 0.02 | | 1 | 1 | <<1 | Methylene chloride | | 0.38 | 0.03 | | 31 | 8.7 | 2.7 | Methyl chloride | | 1.0 | 0.01 | | 45 | 13 | 4 |
‡ SAR refers to the IPCC Second Assessment Report (1995) used for reporting under the UNFCCC. For the magnitude and range of realistic forcings considered, evidence suggests an approximately linear relationship between global mean radiative forcing and global mean surface temperature response. The spatial patterns of radiative forcing vary between different forcing agents. However, the spatial signature of the climate response is not generally expected to match that of the forcing. Spatial patterns of climate response are largely controlled by climate processes and feedbacks. For example, sea ice-albedo feedbacks tend to enhance the high-latitude response. Spatial patterns of response are also affected by differences in thermal inertia between land and sea areas. {2.8, 9.2} The pattern of response to a radiative forcing can be altered substantially if its structure is favourable for affecting a particular aspect of the atmospheric structure or circulation. Modelling studies and data comparisons suggest that mid- to high-latitude circulation patterns are likely to be affected by some forcings such as volcanic eruptions, which have been linked to changes in the Northern Annular Mode (NAM) and North Atlantic Oscillation (NAO) (see Section 3.1 and Box TS.2). Simulations also suggest that absorbing aerosols, particularly black carbon, can reduce the solar radiation reaching the surface and can warm the atmosphere at regional scales, affecting the vertical temperature profile and the large-scale atmospheric circulation. {2.8, 7.5, 9.2} The spatial patterns of radiative forcings for ozone, aerosol direct effects, aerosol-cloud interactions and land use have considerable uncertainties. This is in contrast to the relatively high confidence in the spatial pattern of radiative forcing for the LLGHGs. The net positive radiative forcing in the Southern Hemisphere (SH) very likely exceeds that in the NH because of smaller aerosol concentrations in the SH. {2.9} |
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